I have a Canon S630. I can go Control Panel, Printers, right click my S630 & select Properties, then select the Advanceed Tab, select the Printing Defaults button and finally select the Profiles tab.
Here I can now add profiles which I can set up anything I want. Currently I only have two profiles set up - Photos and Docs. When you go thru the custom set-up to print (like selecting the type of paper, auto color or manual color etc) it gives me the option to "save current profile" - which will put that "new profile" in the list.
I have seen the Copy1 deal that 2Z is talking about - I did it by "mistake" when I was troubleshooting my printer when the power supply in it went bad. I actually had like 3 copies in my control panel because I was trying different drivers.
With the multiple copies, If I remember correctly, you have to go into the control panel/printers and set the copy(for the job you desire) as the default.